By Frank C. Hawthorne, Roberta Oberti, Giancarlo Della Ventura, Annibale Mottana
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Additional info for Amphiboles: Crystal Chemistry, Occurrence, and Health Issues (Reviews in Mineralogy and Geochemistry 67)
A–O distances (Å) in joesmithite*. A–O(5)A A–O(5)B A–O(6)A A–O(6)B A–O(7) * from Moore et al. 937 Figure 32. The arrangement of polyhedra around the A cavity and the A site in the Pnma amphibole structure. Table 11. A–O distances (Å) in anthophyllite and sodicgedrite. 370 * from Schindler et al. , Robinson et al. 1971; Cámara and Oberti 2005). The Pnmn amphiboles In the synthetic protoamphibole reported by Gibbs (1969), the chemical analysis (Gibbs et al. 1960) indicated Li at the A site, but Li could not be located by structure reinement.
27b): the equation of the linear-regression relation is given in Table 8. The slope and intercept of the curve are reasonably similar to the analogous values for the M(4) site in the monoclinic magnesium-iron-manganese-lithium amphiboles (Fig. 27a, Table 8), indicating the same cause for this relation. 72 <
Figure 35 shows that amphiboles do not occupy all available space, and that discrete populations can be identiied which are mainly related to the nature of the B cations. Multiple stepwise linear regression was then done using the unit-cell parameters as dependent variables. Due to the constraint of the full occupancy of the T and M sites, only the following independent chemical constituents were used: AK, A Na, BNa, B(Fe,Mn)2+, BLi, BMg, CAl, CTi, CFe2+, CFe3+, CLi, TAl, WF, WO2−. In this way, the equations predict deviations from ideal tremolite, ̊ Ca2 Mg5 Si8 O22 (OH)2.
Amphiboles: Crystal Chemistry, Occurrence, and Health Issues (Reviews in Mineralogy and Geochemistry 67) by Frank C. Hawthorne, Roberta Oberti, Giancarlo Della Ventura, Annibale Mottana